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staff
Professor
松坂 裕之
Hiroyuki MATSUZAKA
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大阪府立大学大学院 理学系研究科 分子科学専攻
Department of Chemistry, Graduate School of Science, Osaka Prefecture University
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Keywords
Organometallic Chemistry, Coordination Chemistry, Catalysis, Metal Clusters
有機金属化学,錯体化学,触媒,金属クラスター錯体
Employment History
1988 Postdoctoral Fellow, Pennsylvania State University, USA
1989 Assistant Professor, The University of Tokyo
1995 Associate Professor, Tokyo Metropolitan University
2001 Professor, Osaka Prefecture University
Research Summary
1) Organometallic Chemistry of Low-Valent Noble Metal Amido and Imido Clusters
2) Low-Coordinate Ruthenium Carbide Complexes
3) Development of Rational Synthetic Methodology of Homo and Heterobimetallic Cluster Complexes
Selected Publications
  1. A Diruthenium μ-Carbido Complex That Shows Singlet-Carbene-Like Reactivity Takemoto, S.; Ohata, J.; Umetani, K.; Yamaguchi, M.; Matsuzaka, H. J. Am. Chem. Soc. in press. (DOI : http://dx.doi.org/10.1021/ja509364d )
  2. Synthesis and N-H Reductive Elimination Study of Dinuclear Ruthenium Imido Dihydride Complexes Takemoto, S; Yamazaki, Y.; Yamano, T.; Mashima, D.; Matsuzaka, H. J. Am. Chem. Soc. 2012, 134, 17027-17035.
  3. Recent Advances in the Chemistry of Ruthenium Carbido Complexes Takemoto, S. and Matsuzaka, H. Coord. Chem. Rev. 2012, 256, 574-588.
  4. Synthesis and Reactivity of Coordinatively Unsaturated Dinuclear Ruthenium Bridging Imido Complexes Takemoto, S.; Kobayashi, T.; Ito, T.; Inui, A.; Karitani, K.; Katagiri, S.; Masuhara, Y.; Matsuzaka, H. Organometallics 2011, 30, 2160-2172. [Featured as a cover]
  5. A Bimetallic Ru2Pt Complex Containing a Trigonal-Planar 3-Carbido Ligand: Formation, Structure, and Reactivity Relevant to The Fischer-Tropsch Process Takemoto, S.; Morita, H.; Karitani, K.; Fujiwara, H.; Matsuzaka, H. J. Am. Chem. Soc. 2009, 131, 18026-18027.
  6. Divalent Dirhodium Imido Complexes: Formation, Structure, and Alkyne Cycloaddition Reactivity Takemoto, S.; Otsuki, S.; Kamikawa, K.; Matsuzaka, H. J. Am. Chem. Soc. 2008, 130, 8904-8905.
  7. Reactivity of Amido Ligands on a Dinuclear Ru(II) Center: Formation of Imido Complexes and C-N Coupling Reaction with Alkyne Takemoto, S.; Kobayashi, T.; Matsuzaka, H. J. Am. Chem. Soc. 2004, 126, 10802-10803.