発表論文 | 柳日馨研究室 / 大阪府立大学大学院理学研究科分子科学専攻/理学部分子科学科

大阪府立大学  理学部  分子科学科  アクセス  サイトマップ

発表論文

Published in 2000

JACS
Chelation-aided generation of ketone α,β-dianions and their use as copper ate complexes. unprecedented enolate intervention in the conjugate addition to enones
Ryu, I., Nakahira, H., Ikebe, M., Sonoda, N., Yamato, S., Komatsu, M.
J. Am. Chem. Soc., 2000, 122, 6 pp. 1219 - 1220
DOI: 10.1021/ja993577t

Lactone synthesis based on atom transfer carbonylation
Kreimerman, S., Ryu, I., Minakata, S., Komatsu, M.
Org. Lett., 2000, 2, 3 pp. 389 - 391
DOI: 10.1021/ol9913441

Five- to seven-membered lactones were prepared from ω-hydroxyalkyl iodides and CO by atom transfer carbonylation without the need for transition metal catalysts. The reaction proceeds via a hybrid radical/ionic mechanism in which the intramolecular alcoholysis of an ω-hydroxyacyl iodide, arising from atom transfer carbonylation, leads to the lactone.

TL
Selective [2+1] aziridination of conjugated dienes with a nitridomanganese complex: a new route to alkenylaziridines
Nishimura, M., Minakata, S. , Thongchant, S., Ryu, I., Komatsu, M.
Tetrahedron Lett., 2000, 41, 36 pp. 7089 - 7092
DOI: 10.1016/S0040-4039(00)01219-3

Conjugated dienes were successfully aziridinated using a nitridomanganese complex as a nitrogen source. The reaction proceeded selectively and in good yield via [2+1] addition to give alkenylaziridines, with no evidence for the formation of any [4+1] addition products. The first asymmetric version of the reaction was revealed in the aziridination of diene 5 with chiral complex 1.

TL
Conjugate addition of zincates derived from keton α,β-dianions to enones. An access to unsymmetrical 1,6-diketones
Ryu, I., Ikebe, M., Sonoda, N., Yamato, S., Yamamura, G., Komatsu, M.
Tetrahedron Lett., 2000, 41, 30 pp. 5689 - 5692
DOI: 10.1016/S0040-4039(00)00925-4

The conjugate addition of organozincates derived from ketone α,β-dianions to enones was examined. Good yields of unsymmetrical 1,6-diketones were obtained by this reaction. A mixed zincate consisting of the dianion and methyllithium in a 2:1 ratio gave results which were comparable to those of an unmixed dianion zincate.

journal_ec
Epoxidation of olefins mediated by aliphatic ketiminium salts
Minakata, S., Takemiya, A., Nakamura, H., Ryu, I., Komatsu, M.
Synlett, 2000, , pp. 1810 - 1812
DOI: 10.1055/s-2000-8709

TL
Generation and cycloaddition of polymer-supported azomethine imines: traceless synthesis of pyrazole derivatives from alhpasilylnitrosoamide derivatives bound to resin
Wahizuka, K., Nagai, I., Minakata, S., Ryu, I.
Tetrahedron Lett., 2000, 41, 5 pp. 691 - 695
DOI: 10.1016/S0040-4039(99)02140-1

1,3-Dipolar cycloaddition of polymer-supported azomethine imines with dimethyl acetylenedicarboxylate (DMAD) gave pyrazole derivatives in good yields. The azomethine imines were generated from polymer-supported α-silylnitrosoamides by a 1,4-silatropic shift. The feature of this reaction is that no cleavage operations are required after the cycloaddition.

 

 

お問合せ

 

〒599-8531
堺市中区学園町1番1号
大阪府立大学 大学院 理学系研究科

 

TEL&FAX:072-254-9695
Mail:ryu@c.s.osakafu-u.ac.jp
「@」を半角に変換してください。