staff
staff
Professor
柳 日馨
IIhyong RYU
profile photo
大阪府立大学大学院 理学系研究科 分子科学専攻
Department of Chemistry, Graduate School of Science, Osaka Prefecture University
mail icon ryu[@]c.s.osakafu-u.ac.jp
  Please delete []
link button
Keywords
Organic Synthesis, Radical Reactions, Catalysis, Carbonylation Chemistry, Green Sustainable Chemistry, Flow Chemistry
Employment History
1988 Assistant Professor, Osaka University
1991-1992 Visiting Scientist, University of Ottawa
1995 Associate Professor, Osaka University
2000 Professor, Osaka Prefecture University

Awards
1988 Daicel Chemical Award in Synthetic Organic Chemistry, Japan
1990 Progress Award in Synthetic Organic Chemistry, Japan
2004 Chemical Society of Japan Award for Creative Work
2009 ISOFT 09 Award, International Symposium on Fluorous Technology
Research Summary
•New synthetic methodologies based on radical and catalytic reactions
•Utilization of natural resources for the synthesis of useful molecules
• Green reactions and processes
• Microflow reactions for efficiency in organic synthesis
Selected Publications
  1. Sunlight Photocatalyzed Regioselective β-Alkylation and Acylation of Cyclopentanones, M. Okada, T. Fukuyama, K. Yamada, I. Ryu, D. Ravelli, M. Fagnoni, Chem. Sci., 2014, 5, 2893.
  2. Carbonylation Reactions of Alkyl Iodides through the Interplay of Carbon Radicals and Pd Catalysts, S. Sumino, A. Fusano, T. Fukuyama, I. Ryu, Acc. Chem. Res., 2014, 47, 1563.
  3. Borohydride Mediated Radical Addition Reactions of Organic Iodides to Electron-Deficient Alkenes, T. Kawamoto, S. Uehara, H. Hirao, T. Fukuyama, H. Matsubara, I. Ryu, J. Org. Chem., 2014, 79, 3999.
  4. A Bromine-Radical Mediated Three-Component Reaction Comprising Allenes, Electron-Deficient Alkenes and Allyl Bromides: Facile Synthesis of 2-Bromo-1,7-Dienes, T. Kippo, I. Ryu, Chem. Commun., 2014, 50, 5993.
  5. Free-Radical-Mediated [2+2+1] Cycloaddition of Acetylenes, and CO Leading to Five-Membered α,β-Unsaturated Lactams, T. Fukuyama, N. Nakashima, T. Okada, I. Ryu, J. Am. Chem. Soc., 2013, 135, 1006.
  6. Bromine Radical-Mediated Sequential Radical Rearrangement and Addition Reaction of Alkylidenecyclopropanes, T. Kippo, K. Hamaoka, I. Ryu, J. Am. Chem. Soc. 2013, 135, 632.
  7. Synthesis of Alkyl Aryl Ketones by Pd/Light Induced Carbonylative Cross-Coupling of Alkyl Iodides and Arylboronic Acids, S. Sumino, T. Ui, I. Ryu, Org. Lett., 2013, 15, 3142.
  8. Radical Addition of Alkyl Halides to Formaldehyde in the Presence of Cyanoborohydride as a Radical Mediator. A New Protocol for Hydroxymethylation Reaction, T. Kawamoto, T. Fukuyama, I. Ryu, J. Am. Chem. Soc., 2012, 134, 875.
  9. Pd/Light-Accelerated Atom-Transfer Carbonylation of Alkyl Iodides: Applications in Multicomponent Coupling Processes Leading to Functionalized Carboxylic Acid Derivatives A. Fusano, S. Sumino, S. Nishitani, T. Inouye, K. Morimoto, T. Fukuyama, I. Ryu, Chem. Eur. J., 2012, 18, 9415 .
  10. Atom-Economical Synthesis of Unsymmetrical Ketones through Photocatalyzed CH Activation of Alkanes and Coupling with CO and Electrophilic Alkenes, I.Ryu, A. Tani, T. Fukuyama, D. Ravelli, M. Fagnoni, A. Albini, Angew. Chem. Int. Ed., 2011, 50, 1869.